Formulation Material Selection

Halogen-free Flame Retardants: Optimal Selection for Better Performance

Language: English
Length: 90 min
Apr 29, 2025 03:00 PM
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Course Description

Get a grip over your flame-retardant selection strategies by learning about halogen-free alternatives (phosphorus, silicates...) their chemistries & problems with currently available commercial technologies to incorporate for your polymer, adhesives, sealants and coatings applications.

T Richard Hull will help you understand the impact of FR (loading %, toxicity level...) on different polymers and the environment. He will also lay focus on polymer decomposition & FR activity, gas phase flame retardants, cone calorimetry, intumescence and more.

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T Richard Hull
T Richard Hull
University of Central Lancashire (UCLan)
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Richard Hull is a Professor of Chemistry and Fire Science at the University of Central Lancashire (UCLan). 

His work has focussed on fire retardants, fire gas toxicity and fire science.  He has over 100 peer-reviewed publications in fire chemistry, and research income exceeding £2 M. 

His recent work has included unravelling the complexities of the decomposition and burning behaviour of polyetheretherketone (PEEK), stabilised both by carbon fibre and CNTs, using TGA, cone calorimetry and pyrolysis models and the microscale combustion calorimeter, developed at the FAA in the US.  He has pioneered the use of naturally occurring mixtures of huntite and hydromagnesite in EVA cable sheathing as an alternative to the environmentally harmful use of PVC or EVA/ATH (Hungarian red mud catastrophe 2010), and the development of halogen free fire retardant rubber formulations.

He co-edited Fire Retardancy of Polymers: New Strategies and Mechanisms with Prof Kandola from Bolton, published by the Royal Society of Chemistry in 2009, and co-edited a 700 page reference work Fire Toxicity with Dr Anna Stec from UCLan, published by Woodhead/Elsevier in 2010.

Participants of this course includes

Why should you view this course?

Due to increasing environmental consciousness & the pressure to improve product performance, there is a force driving the development of innovative halogen-free flame retardants (> 500 new additives/year).

However, delivering high performing halogen-free flame retardants that meet all the requirements (ecological & performance-wise) is a toughie. Make sure you are equipped with the right FR selection strategies that enhance performance for your polymer, coatings, and adhesives applications. Join this course and:

  1. Assess whether your choice of flame retardants is still relevant by reviewing FR technologies, their pros & cons in terms of cost, plastic property & flammability.

  2. Tailor more easily your plastic performance by better understanding the impact of FR (loading %, toxicity level...) on different polymers and the environment.

  3. Adapt faster to market & regulatory pressure (low smoke, low acidity, recycling...) by getting an unbiased expert insight on commercial solutions available today.

Who should join this course?
  • Particularly suited for Fire Retardant Suppliers & Plastic Formulators seeking solutions to reach higher performance levels.

  • Complete the course and (unlock your personalized certificate)– your badge of accomplishment awaits!

  • This course is suitable for intermediate level proficiency
    Intermediate
Course Outline

Flame retardants in action

  • Drivers in flame retardants development
  • Additive vs reactive FRs
  • Polymer decomposition chemistries & FR activity
  • Specialist applications- Adhesives, Sealants, Coatings

Gas phase flame retardants

  • Halogen FR action & common brominated FRs
  • Requirements of Gas Phase flame retardants
  • Phosphorus, Nitrogen and sulphur as gas phase FRs

Cone calorimetry

Flame retardant mechanisms

  • Charring/non-charring polymers
  • Additives to stabilize char

Intumescence

  • Inorganic phosphates
  • Range of components for intumescents

Nanofillers & polymer nanocomposites

  • Case study – intumescent PLA with nanoclay
  • Layer-by-layer assembly

Phosphorus-based chemistries

  • Modes of FR action
  • Case study – phosphorus comonomers in epoxy resins

Other chemistries including silicates and boron

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30 min Q & As for this course
Interact directly with your tutor and clarify your doubts
  1. 30 mins per session for Questions and Answers
  2. Clarify your doubts.
  3. If your questions are not answered, dont worry you will recieve tutor’s reply via email after sessions.
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